A Total Synthesis of Dimethyl 2,3-O-Isopropylidene-l-O-oxalyl-β-DL-ribo-hexofuran-5-ulosuronate
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A stereoselective total synthesis of 7,8-O-isopropylidene iriomoteolide-3a.
A stereoselective total synthesis of 7,8-O-isopropylidene iriomoteolide-3a has been achieved by using Yamaguchi esterification, Julia-Kocienski olefination, organocatalytic α-oxidation, and ring-closing metathesis reaction as key bond-forming steps.
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Rights: © 2001 American Physical Society (APS). This is the accepted version of the following article: Karppinen, M. & Kotiranta, Maarit & Yamauchi, H. & Nachimuthu, P. & Liu, R. S. & Chen, J. M. 2001. O K -edge and CuL23-edge XANES study on the concentration and distribution of holes in the (Pb2/3Cu1/3)3Sr2(Y ,Ca)Cu2O8+z superconductive phase. Physical Review B. Volume 63, Issue 18. 184507/1-6...
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In the title centrosymmetric dinuclear nickel complex, [Ni(2)(C(22)H(30)N(4)O(2))(NO(3))(2)], each of the two Ni(II) atoms has a distorted octa-hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bridged by two phenolate O atoms, forming a four-membered Ni(2)O(2) ring.
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1975
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v75-383